発表論文

  • 60) "A Four Coordinated Iron(II)-Digermyl Complex as an Effective Precursor for the Catalytic Dehydrogenation of Ammonia Borane"
    Kobayashi, Y.; Sunada, Y. Catalysts, in press.
  • 59) "Theoretical Study on the Rhodium-Catalyzed Hydrosilylation of C═C and C═O Double Bonds with Tertiary Silane"
    Zhao, L.; Nakatani, N.; Sunada, Y.; Nagashima, H.; Hasegawa, J. J. Org. Chem. 2019, 84, 8552-8561.
  • 58) "Dimensionality Expansion of a Butterfly Shaped Pd4 Framework: Constructing Edge-Sharing Pd6 Tetrahedra"
    Shimamoto, K.; Sunada, Y. Chem. Eur. J. 2019, 25, 3761-3765.
  • 57) "An isolable iron(II) bis(supersilyl) complex as an effective catalyst for reduction reactions"
    Arata, S.; Sunada, Y. Dalton Trans. 2019, 48, 2891-2895.
  • 56) "Iridium-PPh3 Catalysts for Conversion of Amides to Enamines"
    Une, Y.; Tahara, A.; Miyamoto, Y.; Sunada, Y.; Nagashima, H. Organometallics 2019, 38, 852-862.
  • 55) "Syntheses of Substituted 1,4-Disila-2,5-cyclohexadienes from Cyclic Hexasilane Si6Me12 and Alkynes via Successive Si–Si Bond Activation by Pd/Isocyanide Catalysts"
    Tahara, T.; Nagino, S.; Sunada, Y.; haige, R.; Nagashima, H. Organometallics 2018, 37, 2531-2543.
  • 54) "Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds"
    Tahara, A.; Sunada, Y.; Takeshita, T.; Inoue, R.; Nagashima, H. Chem. Commun., 2018, 54, 11192-11195.
  • 53) "Radical-Organometallic Hybrid Reaction System Enabling Couplings between Tertiary-Alkyl Groups and 1-Alkenyl Groups"
    Nakamura, K.; Hara, R.; Sunada, Y.; Nishikata, T. ACS Catal., 2018, 8, 6791-6795.
  • 52) "Disilaruthena- and Ferracyclic Complexes Containing Isocyanide Ligands as Effective Catalysts for Hydrogenation of Unfunctionalized Sterically Hindered Alkenes"
    Sunada, Y.; Ogushi, H.; Yamamoto, T.; Uto, S.; Sawano, M.; Tahara, A.; Tanaka, H.; Shiota, Y.; Yoshizawa, K.; Nagashima, H. J. Am. Chem. Soc., 2018, 140, 4119–4134.
  • 51) "平面状Pdクラスター分子における配位子交換反応"
    谷山暢啓、*砂田祐輔、生産研究、2018, 70, 51-53.
  • 50) "貴金属代替を指向した鉄触媒設計と触媒反応開発"(総合論文)
    *砂田祐輔、*永島英夫 有機合成化学協会誌 2017, 75, 1253-1263.
  • 49) "Construction of a Planar Tetrapalladium Cluster by the Reaction of Palladium(0) Bis(isocyanide) with Cyclic Tetrasilane"(invited)
    *Sunada, Y.; Taniyama, N.; Shimamoto, K.; Kyushin, S.; Nagashima, H. Inorganics 2017, 5, 84.
  • 48) "Copper-​Catalyzed Amination of Congested and Functionalized α-​Bromocarboxamides with either Amines or Ammonia at Room Temperature"
    Ishida, S.; Takeuchi, K.; Taniyama, N.; Sunada, Y.; Nishikata, T. Angew. Chem. Int. Ed., 2017, 56, 11610-11614.
  • 47) "σ-​CAM mechanisms for the hydrogenation of alkenes by cis- and trans-​disilametallacyclic carbonyl complexes (M = Fe, Ru, Os)​: experimental and theoretical studies"
    Hoshi, K.; Tahara, A.; Sunada, Y.; Tsutsumi, H.; Inoue, R.; Tanaka, H.; Shiota, Y.; Yoshizawa, K.; Nagashima, H. Bull. Chem. Soc. Jpn., 2017, 90, 613-626.
  • 46) "Disilametallacyclic chemistry for efficient catalysis"
    Sunada, Y.; Nagashima, H. Dalton. Trans., 2017, 46, 7644-7655.
  • 45) "Theoretical Study of the Catalytic Hydrogenation of Alkenes by a Disilaferracyclic Complex: Can the Fe-​Si σ-​Bond-​Assisted Activation of H-​H Bonds Allow Development of a Catalysis of Iron?"
    Tahara, A.; Tanaka, H.; Sunada, Y.; Shiota, Y.; Yoshizawa, K.; Nagashima, H. J. Org. Chem., 2017, 81, 10900-10911.
  • 44) "Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes"
    Noda, D.; Tahara, A.; Sunada, Y.; Nagashima, H. J. Am. Chem. Soc., 2016, 138, 2480-2483.
  • 43) "Theoretical Study of Pd11Si6 Nanosheet Compounds Including Seven-Coordinated Si Species and Its Ge Analogues"
    Chen, Y.; Sunada, Y.; Nagashima, H.; Sakaki, S. Chem. Eur. J., 2016, 22, 1076-1087.
  • 42) "Atom transfer radical polymerization by solvent-stabilized (Me3TACN)FeX2: a practical access to reusable iron(II) catalysts"
    Nakanishi, S.; Kawamura, M.; Sunada, Y.; Nagashima, H. Polym. Chem., 2016, 7, 1037-1048.
  • 41) "Platinum- catalyzed reduction of amides with hydrosilanes bearing dual Si-H groups: a theoretical study of the reaction mechanism"
    Nakatani, N.; Hasegawa, J.; Sunada, Y.; Nagashima, H. Dalton Trans.., 2015, 44, 19344-19356.
  • 40) "Persistent four-coordinate iron-centered radical stabilized by π-donation"
    Sunada, Y.; Ishida, S.; Hirakawa, F.; Shiota, Y.; Yoshizawa, K.; Kanegawa, S.; Sato, O.; Nagashima, H.; Iwamoto, T. Chem. Sci., 2016, 7, 191-198.
  • 39) "Catalyst Design of Vaska-Type Iridium Complexes for Highly Efficient Synthesis of π-Conjugated Enamines"
    Tahara, A.; Miyamoto, Y.; Aoto, R.; Shigeta, K.; Une, Y.; Sunada, Y.; Motoyama, Y.; Nagashima, H. Organometallics 2015, 34, 4895-4907.
  • 38) "A Combinatorial Approach to the Catalytic Hydrosilylation of Styrene Derivatives: Catalyst Systems Composed of Organoiron(0) or (II) Precursors and Isocyanides"
    Sunada, Y.; Noda, D.; Soejima, H.; Tsutsumi, H.; Nagashima, H. Organometallics 2015, 34, 2896-2906.
  • 37) "Investigation of Organoiron Catalysis in KumadaTamaoCorriu-Type Cross-Coupling Reaction Assisted by Solution-Phase X-ray Absorption Spectroscopy"
    Takaya, H.; Nakajima, S.; Nakagawa, N.; Isozaki, K.; Iwamoto, T.; Imayoshi, R.; Gower, N. J.; Adak, L.; Hatakeyama, T.; Honma, T.; Takagaki, M.; Sunada, Y.; Nagashima, H.; Hashizume, D.; Takahashi, O.; Nakamura, M. Bull. Chem. Soc. Jpn., 2015, 88, 410-418.
  • 36) "A Disilaferracycle Dicarbonyl Complex Containing Weakly Coordinated η2-(H-Si) Ligands: Application to C-H Functionalization of Indoles and Arenes"
    Sunada, Y.; Soejima, H.; Nagashima, H. Organometallics 2014, 33, 5936-5939.
  • 35) "Synthesis, Structures, and Reactivity of the Base-Stabilized Silanone Molybdenum Complexes"
    Muraoka, T.; Abe, K.; Kimura, H.; Haga, Y.; Ueno, K.; Sunada, Y. Dalton Trans., 2014, 43, 16610-16613.
  • 34) "Well-Defined Iron Complexes as Efficient Catalysts for "Green" Atom-Transfer Radical Polymerization of Styrene, Methyl Methacrylate, and Butyl Acrylate with Low Catalyst Loadings and Catalyst Recycling"
    Nakanishi, S.; Kawamura, M.; Kai, H.; Jin, R. –H.; Sunada, Y.; Nagashima, H. Chem. Eur. J., 2014, 20, 5802-5814.
  • 33) "A Ladder Polysilane as a Template for “Folding” Palladium Nanosheets"
    Sunada, Y.; Haige, R.; Otsuka, K.; Kyushin, S.; Nagashima, H. Nature Communnications., 2013, 4, 3014/1-3014/7.
  • 32) "Catalyst design for iron-promoted reductions: an iron disilyl-dicarbonyl complex bearing weakly coordinating η2-(H-Si) moieties"
    Sunada, Y.; Tsutsumi, H.; Shigeta, K.; Yoshida, R.; Hashimoto, T.; Nagashima, H. Dalton Trans., 2013, 42, 16687-16692.
  • 31) "Disilametallacycles as a Platform for Stabilizing M(II) and M(IV) (M = Fe, Ru) Centers: Synthesis and Characterization of Half-Sandwich Complexes and Their Application to Catalytic Double Silylation of Alkenes and Alkynes"
    Sunada, Y.; Imaoka, T.; Nagashima, H. Organometallics 2013, 32, 2112-2120.
  • 30) "Iron promoted conjugate addition: implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate"
    Noda, D.; Sunada, Y.; Hatakeyama, T.; Nakamura, M.; Nagashima, H. Chem. Commun., 2012, 48, 12231-12233.
  • 29) "New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides"
    Tsutsumi, H.; Sunada, Y.; Nagashima, H. Chem. Commun., 2011, 47, 6581-6583.
  • 28) "Novel Disilaplatinacyclopentenes Bearing Dialkylsulfide Ligands: Preparation, Characterization, and Mechanistic Consideration of Hydrosilane Reduction of Carboxamides by Bifunctional Organohydrosilanes"
    Tsutsumi, H.; Sunada, Y.; Nagashima, H. Organometallics 2011, 30, 68-76.
  • 27) "Chiral Bis(oxazoline) Ruthenium Complexes with Bipyridyl-Type N-Heteroaromatics: Comparative Stereochemical and Photochemical Characterization of their L- and D-Diastereomeric Geminate Isomers"
    Onishi, M.; Tashiro, Y.; Arikawa, Y.; Nagaoka, J.; Umakoshi, K.; Sunada, Y.; Nozaki, K. Chem. Asian. J., 2011, 6, 1405-1415.
  • 26) "Half-Sandwich (η6-Arene)iron(II) Dinitrogen Complexes Bearing a Disilaironacycle Skeleton as a Precursor for Double Silylation of Ethylene and Alkynes"
    Sunada, Y.; Imaoka, T.; Nagashima, H. Organometallics 2010, 29, 6157-6160.
  • 25) "Catalyst Design of Novel Nickellacyclic Complexes for Ethylene Polymerization"
    Tanabiki, M.; Matsubara, K.; Sunada, Y.; Nagashima, H. Journal of Novel Carbon Resource Sciences, 2010, 1, 16-23.
  • 24) "Hydrosilane Reduction of Tertiary Carboxamides by Iron Carbonyl Catalysts"
    Sunada, Y.; Kawakami, H.; Imaoka, T.; Motoyama, Y.; Nagashima, H. Angew. Chem. Int. Ed. 2009, 48, 9511-9514.
  • 23) "New Fe(II)-complexes for Atom Transfer Radical Polymerization: The Ligand Design for TACN Results in High Reactivity and Catalyst Performance"
    Kawamura, M.; Sunada, Y.; Kai, H.; Koike, N.; Hamada, A.; Hayakawa, H.; Jin, R. -H.; Nagashima, H. Adv. Synth Catal., 2009, 351, 2086-2090.
  • 22) "Mono- and Bimetallic Ethylene Polymerization Catalysts Having an Azanickellacyclopentene Skeleton"
    Noda, D.; Tanabiki, M.; Tsuchiya, K.; Sunada, Y.; Nagashima, H. Polyhedron 2009, 28, 3935-3944.
  • 21) "Effect of TMEDA on Iron-Catalyzed Coupling Reactions of ArMgX with Alkyl Halides"
    Noda, D.; Sunada, Y.; Hatakeyama, T.; Nakamura, M.; Nagashima, H. J. Am. Chem. Soc., 2009, 131, 6078-6079.
  • 20) "(η3-Allyl)Ni(II), Pd(II), and Pt(II) Complexes Bearing a Bidentate Titanium(IV) Phosphinoamide Ligand: a Ti ← M2 Dative Bond Enhances the Electrophilicity of the π-Allyl Moiety"
    Tsutsumi, H.; Sunada, Y.; Shiota, Y.; Yoshizawa, K.; Nagashima. H. Organometallics 2009, 28, 1988-1991.
  • 19) "Two coordination modes of TCNE in the ruthenium amidinates: The first example providing experimental evidence for κ1-N to η2-C rearrangement"
    Kondo, H.; Sue, T.; Kageyama, A.; Yamaguchi, Y.; Sunada, Y.; Nagashima, H. J. Organomet. Chem., 2009, 694, 795-800.
  • 18) "Synthesis, Structures, and Electronic Properties of [8Fe-7S] Cluster Complexes Modeling the Nitrogenase P-Cluster"
    Ohki, Y.; Imada, M.; Murata, A.; Sunada, Y.; Ohta, S.; Honda, M.; Sasamori, T.; Tokitoh, N.; Katada, M.; Tatsumi, K. J. Am. Chem. Soc., 2009, 131, 13168-13178.
  • 17) "Rotation of Ethylene Molecule on the Oragnometallic Species: A Possibility to Control the Rotation Rate"
    Kondo, H.; Hayashida, T.; Yamaguchi, Y.; Sunada, Y.; Nagashima, H. Engineering Sciences Reports, Kyushu University, 2008, 30, 307-312.
  • 16) "Synergistic Effects of Two Si-H Groups and a Metal Center" in Transition Metal-Catalyzed Hydrosilylation of Unsaturated Molecules: A Mechanistic Study of the RhCl(PPh3)3-Catalyzed Hydrosilylation of Ketones with 1,2-Bis(dimethylsilyl)benzene"
    Sunada, Y.; Fujimura, Y.; Nagashima, H. Organometallics 2008, 27, 3502-3513.
  • 15) "Experimental and theoretical aspects of the haptotropic rearrangement of diiron and diruthenium carbonyl complexes bound to 4,6,8-trimethylazulene"
    Tsuchiya, K.; Ideta, K.; Mogi, K.; Sunada, Y.; Nagashima, H. Dalton Trans., 2008, 2708-2716.
  • 14) "A bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me3Si(C=NAr)SiMe2(C=NAr)SiMe3 (Ar = 2,6-xylyl), as a New β-Diimine Ligand"
    Tanabiki, M.; Sunada, Y.; Nagashima, H. Organometallics 2007, 26, 6055-6058.
  • 13) "Zirconium(IV) Tris(phosphinoamide) Complexes as the Tripod-type Metalloligand: A Novel Route to Zr-M (M = Cu, Mo, Pt) Heterobimetallic Complexes"
    Sue, T.; Sunada, Y.; Nagashima, H. Eur. J. Inorg. Chem., 2007, 18, 2897-2908.
  • 12) "Trifluoromethanesulfonate (triflate) as a moderately coordinating anion: Studies from chemistry of the cationic coordinatively unsaturated mono- and diruthenium amidinates"
    Hayashida, T.; Kondo, H.; Terasawa, J.; Kirchner, K.; Sunada, Y.; Nagashima, H. J. Organomet. Chem., 2007, 692, 382-394.
  • 11) "Theory of chemical bonds in metalloenzymes V: hybrid-DFT studies of the inorganic [8Fe-7S] core"
    Shoji, M.; Koizumi, K.; Kitagawa, Y.; Yamanaka, S.; Okumura, M.; Yamaguchi, K.; Ohki, Y.; Sunada, Y.; Honda, M.; Tatsumi, K. International Journal of Quantum Chemistry 2006, 106, 3288-3302.
  • 10) "Titanium(IV) phosphinoamide as a unique bidentate ligand for late transition metals II: TiRu heterobimetallics bearing a bridging chlorine atom"
    Sunada, Y.; Sue, T.; Matsumoto, T.; Nagashima, H. J. Organomet. Chem., 2006, 691, 3176-3182.
  • 9) "Dynamic Titanium Phosphinoamides as Unique Bidentate Phosphorus Ligands for Platinum"
    Nagashima, H.; Sue, T.; Oda, T.; Kanemitsu, A.; Matsumoto, T.; Motoyama, Y.; Sunada, Y. Organometallics 2006, 25, 1987-1994.
  • 8) "Synthesis of [2Fe-2S] and [4Fe-4S] Clusters Having Terminal Amide Ligands from an Iron(II) Amide Complex"
    Ohki,Y.; Sunada, Y.; Tatsumi, K. Chem. Lett., 2005, 34, 172-173.
  • 7) "Quasi-octahedral complexes of pentamethylcyclopentadienyliridium(III) bearing bis(diphenylphosphinomethyl)phenylphosphine (dpmp)"
    Yamamoto, Y.; Kosaka, Y.; Tsutsumi, Y.; Sunada, Y.; Tatsumi,K.; Takei, F.; Takahashi, S. Dalton Trans., 2004, 2969-2978.
  • 6) "Reactions of rhodium(II) and iridium(III) complexes bearing a P,O-coordination with tetracyanoethylene in the presence of KPF6"
    Yamamoto, Y.; Takahashi, A.; Sunada, Y.; Tatsumi. K. Inorg. Chim. Acta., 2004, 357, 2833-2840.
  • 5) "Homo- and heteronuclear complexes based on arene ruthenium complexes bearing bis(diphenylphosphinomethyl)phenylphosphine (dpmp)"
    Yamamoto, Y.; Shinozaki, Y.; Tsutsumi, Y.; Fuse, K.; Kuge, K.; Sunada, Y.; Tatsumi, K. Inorg. Chim. Acta., 2004, 357, 1270-1282.
  • 4) "Homo- and Heteronuclear Complexes of (Pentamethylcyclopentadienyl)-rhodium(III) Bearing [Bis(diphenylphosphanylmethyl)]phenylphosphane"
    Yamamoto, Y.; Kosaka, Y.; Shinozaki, Y.; Tsutsumi, Y.; Kaburagi, Y.; Kuge, K.; Sunada, Y.; Tatsumi, K. Eur. J. Inorg. Chem., 2004, 134-142.
  • 3) "Synthesis of the P-Cluster Inorganic Core of Nitrogenases"
    Ohki, Y.; Sunada, Y.; Honda, M.; Katada, M.; Tatsumi, K. J. Am. Chem. Soc., 2003, 125, 4052-4053.
  • 2) "Streochemistry of mono- and dinuclear complexes of rhodium, iridium and ruthenium bearing bis(diphenylphosphinomethyl)phenylphosphine"
    Kosaka, Y.; Shinozaki, Y.; Tsutsumi, Y.; Kaburagi, Y.; Yamamoto, Y.; Sunada, Y.; Tatsumi, K. J. Organomet. Chem., 2003, 671, 8-12.
  • 1) "Alkynethiolato and Alkyneselenolato Ruthenium Half-sandwich Complexes: Synthesis, Structures, and Reactions with (η5-C5H5)2Zr"
    Sunada, Y.; Hayashi, Y.; Kawaguchi, H.; Tatsumi, K. Inorg. Chem., 2001, 40, 7072-7078.

連絡先

東京大学
生産技術研究所 物質・環境系部門
機能性金属クラスター科学分野
砂田研究室

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sunada(at)iis.u-tokyo.ac.jp
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